Paraná/PR 1-4 Atlético/PR *
| 14.09.2006 | Atlético/PR | 1-0 | Paraná/PR | |
| 07.09.2006 | Paraná/PR | 1-3 | Atlético/PR | |
*Universitario Sucre 5-4 Bolívar
| 01.09.2006 | Bolívar | 2-3 | Universitario Sucre | |
| 25.08.2006 | Universitario Sucre | 2-2 | Bolívar | |
*San Lorenzo 2-1 CA Banfield
| 13.09.2006 | CA Banfield | 0-0 | San Lorenzo | |
| 23.08.2006 | San Lorenzo | 2-1 | CA Banfield | |
*CA Lanús 3-0 Vélez Sársfield
| 21.09.2006 | Vélez Sársfield | 0-1 | CA Lanús | |
| 31.08.2006 | CA Lanús | 2-0 | Vélez Sársfield | |
*Mineros Guyana 6-1 Carabobo FC
| 30.08.2006 | Carabobo FC | 1-3 | Mineros Guyana | |
| 23.08.2006 | Mineros Guyana | 3-0 | Carabobo FC | |
*Club Libertad 4-1 Cerro Porteño
| 30.08.2006 | Cerro Porteño | 0-1 | Club Libertad | |
| 24.08.2006 | Club Libertad | 3-1 | Cerro Porteño | |
CD Huachipato 3-3 Colo Colo *
| 01.09.2006 | Colo Colo | 1-2/p.5-3 | CD Huachipato | |
| 25.08.2006 | CD Huachipato | 1-2 | Colo Colo | |
*Coronel Bolognesi 3-3 Univ San Martín
| 31.08.2006 | Univ San Martín | 3-2 | Coronel Bolognesi | |
| 25.08.2006 | Coronel Bolognesi | 1-0 | Univ San Martín | |
*Deportes Tolima 4-2 Independiente Medellín
| 30.08.2006 | Independiente Medellín | 1-1 | Deportes Tolima | |
| 24.08.2006 | Deportes Tolima | 3-1 | Independiente Medellín | |
LDU Quito 3-4 El Nacional Quito *
| 30.08.2006 | El Nacional Quito | 1-1 | LDU Quito | |
| 22.08.2006 | LDU Quito | 2-3 | El Nacional Quito | |
Botafogo/RJ 2-2 Fluminense/RJ *
| 15.09.2006 | Fluminense/RJ | 1-1/p.4-2 | Botafogo/RJ | |
| 08.09.2006 | Botafogo/RJ | 1-1 | Fluminense/RJ | |
Central Español 0-1 Nacional (URU) *
| 29.08.2006 | Nacional (URU) | 0-0 | Central Español | |
| 24.08.2006 | Central Español | 0-1 | Nacional (URU) | |
*Santos/SP 1-1 Cruzeiro/MG
| 14.09.2006 | Cruzeiro/MG | 1-0/p.3-4 | Santos/SP | |
| 07.09.2006 | Santos/SP | 1-0 | Cruzeiro/MG | |
Vasco da Gama/RJ 1-4 Corinthians/SP *
| 14.09.2006 | Corinthians/SP | 3-1 | Vasco da Gama/RJ | |
| 07.09.2006 | Vasco da Gama/RJ | 0-1 | Corinthians/SP | |