Borussia Dortmund 1-2 Chelsea *
| 07.03.2023 | Chelsea | 2-0 | Borussia Dortmund | |
| 15.02.2023 | Borussia Dortmund | 1-0 | Chelsea | |
Eintracht Frankfurt 0-5 SSC Napoli *
| 15.03.2023 | SSC Napoli | 3-0 | Eintracht Frankfurt | |
| 21.02.2023 | Eintracht Frankfurt | 0-2 | SSC Napoli | |
*Inter Milan 1-0 FC Porto
| 14.03.2023 | FC Porto | 0-0 | Inter Milan | |
| 22.02.2023 | Inter Milan | 1-0 | FC Porto | |
Liverpool 2-6 Real Madrid *
| 15.03.2023 | Real Madrid | 1-0 | Liverpool | |
| 21.02.2023 | Liverpool | 2-5 | Real Madrid | |
RB Leipzig 1-8 Manchester City *
| 14.03.2023 | Manchester City | 7-0 | RB Leipzig | |
| 22.02.2023 | RB Leipzig | 1-1 | Manchester City | |
Paris St. Germain 0-3 Bayern München *
| 08.03.2023 | Bayern München | 2-0 | Paris St. Germain | |
| 14.02.2023 | Paris St. Germain | 0-1 | Bayern München | |
Club Brugge 1-7 SL Benfica *
| 07.03.2023 | SL Benfica | 5-1 | Club Brugge | |
| 15.02.2023 | Club Brugge | 0-2 | SL Benfica | |